Siamak Shoja, Materials Science


Title of thesis: Microstructure and plastic deformation of textured CVD alumina coatings.

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It is known that the wear performance of α-alumina coatings produced by chemical vapor deposition (CVD) is significantly influenced by the type and degree of texture. However, the main reasons behind this behavior are not fully understood. This thesis contains studies of two related topics for increasing the understanding of α-alumina coatings. The first topic concerns the microstructure and texture development of CVD α-Al2O3 coatings, and the second topic concerns calculations and analysis of the Schmid factors (m) for coatings with different textures. By combining different analysis methods (such as XRD, SEM, FIB/SEM, TKD, TEM, STEM, XEDS), and theoretical and experimental Schmid factor analysis by MATLAB and EBSD, the microstructure and plastic deformation of α-alumina coatings were investigated.

The microstructures of three different CVD α-Al2O3 layers deposited onto a Ti(C,N,O) bonding layer were studied. Grain boundary diffusion of heavy elements from the substrate to the bonding layer/α-Al2O3 interface was observed. This may be the cause of a disturbance in the early growth of α-Al2O3. Additionally, it was found that the number of interfacial pores at the bonding layer/α-Al2O3 interface increased by introducing the H2S gas. The H2S gas also promoted an earlier development of the (0001) texture. The orientation of the grains was developed to the desired texture both as a gradual change over several grains and as an abrupt transformation from one grain to another.

The probability of plastic deformation in different wear zones on the rake face of a cutting tool was investigated theoretically and experimentally by analyzing Schmid factors for textured α-Al2O3 coatings. Schmid factor diagrams were constructed using MATLAB/MTEX and used to extract frequency distributions for different slip systems and textures. The results were compared with lateral distribution maps of Schmid factors obtained from experimental coatings. It was observed that basal slip is most easily activated in the transition zone, followed by prismatic slip systems 1 and 2 in coatings with an (0001)-texture. The homogeneous plastic deformation behavior observed in this coating is also connected to mostly high Schmid factors in the m-value distribution. The differences between the m-value distributions for the three slip systems are not that pronounced in the (011 ̅​2) and (112 ̅0) textures, and the distributions are relatively wide. The low wear rate and more homogeneous deformation of the coating with (0001) texture compared to the other coating textures may be the result of the high plasticity, offered by the easy activation of basal slip and prismatic 1 slip, and the low spread of Schmid factor values at the transition zone.
In conclusion, the results presented in this thesis form a knowledge platform that can be used to understand the microstructure and wear mechanisms of textured CVD α-alumina coatings.
M​ain Supervisor: Mats Halvarsson
Examiner: Lena Falk
Reviewer: Staffan Jacobson
Category Licentiate seminar
Location: Online via Zoom
Starts: 29 October, 2020, 10:00
Ends: 29 October, 2020, 12:00

Published: Thu 15 Oct 2020.